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《中国科学:材料》2022年第3期

中国科学材料 中国科学材料 2023-02-01



Cover Story Sr-doped LaMnO3 (LSM) is one of the most classical cathode materials for solid oxide fuel cells (SOFCs), but their instinct properties only feature atisfactory performance at high temperatures, which restricts their application for proton-conducting SOFCs (H-SOFCs) that could work at intermediate temperatures. Exploring the strategy of re-using LSM-based cathodes for H-SOFCs is highly desirable and challenging. Bi et al. use Zn ions to tailor traditional LSM and obtain a new material (Zn and Sr co-doped LaMnO3 (LSMZn)). The improved hydration ability of LSMZn leads to facile transportation of protons and thus enables high performance for the LSMZn-based cell, revealing a suitable strategy to bring back LSM based cathodes to the H-SOFCs community (see the article on page 675).


01

REVIEW

Role of binary metal chalcogenides in extending the limits of energy storage systems: Challenges and possible solutions

二元金属硫族化合物在能源储存体系中的作用: 挑战和可能的解决策略

Muhammad Yousaf, Ufra Naseer, Imran Ali, Yiju Li, Waseem Aftab, Asif Mahmood, Nasir Mahmood, Peng Gao(高鹏), Yinzhu Jiang(姜银珠), Shaojun Guo(郭少军)

Sci China Mater, 2022, 65(3): 559



02

REVIEW

Advances in organic micro/nanocrystals with tunable physicochemical Properties

基于有机微/纳米晶体形貌和光学性质的可控调制

Yingxin Ma, Zhi-Zhou Li, Hongtao Lin(蔺红桃), Shuhai Chen(陈淑海), Shuping Zhuo, Xue-Dong Wang(王雪东) 

Sci China Mater, 2022, 65(3): 593–611


03

ARTICLE

Highly efficient Cu2ZnSn(S,Se)4 bifacial solar cell via a composition gradient strategy through the molecular ink

基于成分梯度策略制备高效率铜锌锡硫硒双面电池

Saqib Nawaz Khan, Sijie Ge, Yuxiang Huang, Han Xu, Wentao Yang, Ruijiang Hong, Yaohua Mai, Ening Gu(顾鄂宁), Xianzhong Lin(林显忠), Guowei Yang

Sci China Mater, 2022, 65(3): 612–619


04

ARTICLE

Enhancing the reversible capacity and cycle stability of lithium-ion batteries with Li-compensation material Li6CoO4

补锂材料Li6CoO4提高锂离子电池容量和循环性能

Ziyu Na, Chao Lai, Jiang Zhou, Hongzhou Zhang(张洪周), Dawei Song, Xixi Shi, Lianqi Zhang(张联齐)

Sci China Mater, 2022, 65(3): 620–628


05

ARTICLE

Artificial cathode solid electrolyte interphase to endow highly stable lithium storage of FeF2 nanocrystals

人工正极固体电解质膜赋予FeF2纳米晶正极材料良好的储锂循环稳定性

Ming Chen, Liang Zhao, Xiaomin Li, Xuejiao Liu, Jiantao Zai(宰建陶), Rongrong Qi(戚嵘嵘), Xuefeng Qian(钱雪峰)

Sci China Mater, 2022, 65(3): 629–636


06

ARTICLE

A unique co-recovery strategy of cathode and anode from spent LiFePO4 battery

废旧磷酸铁锂电池的正负极同步再利用策略

Kai-Di Du, Yun-Feng Meng, Xin-Xin Zhao, Xiao-Tong Wang, Xiao-Xi Luo, Wei Zhang, Xing-Long Wu(吴兴隆)

Sci China Mater, 2022, 65(3): 637–645


07

ARTICLE

Achieving superior high-temperature sodium storage performance in a layered potassium vanadate

层状钒酸钾应用于高性能高温钠离子电池

Dong Chen, Yafei Cheng, Hongge Pan, Wenping Sun, Hongbo Geng(耿洪波), Xianhong Rui(芮先宏)

Sci China Mater, 2022, 65(3): 646–652


08

ARTICLE

Self-catalyzed growth of Zn/Co-N-C carbon nanotubes derived from metal-organic frameworks as efficient oxygen reduction catalysts for Zn-air battery

MOFs衍生自催化生长Zn/Co-N-C碳纳米管用作锌空气电池高效氧还原催化剂

Jing Zhang, Ye Chen, Yang Liu, Xupo Liu(刘旭坡), Shuyan Gao(高书燕)

Sci China Mater, 2022, 65(3): 653–662


09

ARTICLE

Artificial solid-electrolyte interface facilitating uniform Zn deposition by promoting chemical adsorption

构筑具有高效化学吸附作用的人工固体电解质界面层促进金属锌负极的均匀沉积

Jingjing Zhang, Wei Peng, Junhong Jin, Shenglin Yang, Aishui Yu(余爱水), Guang Li(李光)

Sci China Mater, 2022, 65(3): 663–674


10

ARTICLE

High-performance proton-conducting solid oxide fuel cells using the first-generation Sr-doped LaMnO3 cathode tailored with Zn ions

通过Zn调节第一代Sr掺杂的LaMnO3阴极制备高性能质子导体固体氧化物燃料电池

Shuai Wu, Xi Xu, Xiaomei Li, Lei Bi(毕磊)

Sci China Mater, 2022, 65(3): 675–682


11

ARTICLE

Anion exchange membranes based on long side-chain quaternary ammonium-functionalized poly(arylene piperidinium)s for vanadium redox flow batteries

长侧链季铵基团功能化聚(亚芳基-哌啶鎓盐)阴离子交换膜的制备及在全钒液流电池中的应用

Xuefu Che, Weiqin Tang, Jianhao Dong, David Aili, Jingshuai Yang(杨景帅)

Sci China Mater, 2022, 65(3): 683–694


12

ARTICLE

Achieving highly stable Sn-based anode by a stiff encapsulation heterostructure

牢固的封装异质结构实现锡基负极的长循环稳定性

Ruizhe Li, Jijian Xu, Zhuoran Lv, Wujie Dong(董武杰), Fuqiang Huang(黄富强)

Sci China Mater, 2022, 65(3): 695–703


13

ARTICLE

1D PtCo nanowires as catalysts for PEMFCs with low Pt loading

一维PtCo纳米线作为低Pt负载PEMFC的催化剂

Jin Huang, Bosi Peng, Thomas Stracensky, Zeyan Liu, Ao Zhang, Mingjie Xu, Yang Liu, Zipeng Zhao, Xiangfeng Duan, Qingying Jia, Yu Huang(黄昱)

Sci China Mater, 2022, 65(3): 704–711


14

ARTICLE

Phosphorus-doped MoS2 with sulfur vacancy defects for enhanced electrochemical water splitting

具有硫空位的磷掺杂二硫化钼用于增强电化学水分解

Hongyao Xue, Alan Meng, Chunjun Chen(陈春俊), Hongyan Xue, Zhenjiang Li(李镇江), Chuansheng Wang(汪传生)

Sci China Mater, 2022, 65(3): 712–720


15

ARTICLE

Bacterial cellulose-regulated synthesis of metallic Ni catalysts for high-efficiency electrosynthesis of hydrogen peroxide

细菌纤维素调控合成金属镍催化剂用于高效电合成过氧化氢

Hui Xu, Meng Jin, Jing Geng, Shengbo Zhang(张圣波), Haimin Zhang(张海民)

Sci China Mater, 2022, 65(3): 721–731


16

ARTICLE

Hybrid 1D/2D heterostructure with electronic structure engineering toward high-sensitivity and polarization-dependent photodetector

混合1D/2D异质结构耦合电子结构工程用于高灵敏度和偏振依赖的光电探测器

Yuchen Zhou, Lixiang Han, Qiqi Song, Wei Gao, Mengmeng Yang, Zhaoqiang Zheng(郑照强), Le Huang, Jiandong Yao, Jingbo Li(李京波)

Sci China Mater, 2022, 65(3): 732–740


17

ARTICLE

Threshold voltage modulation in monolayer MoS2 field-effect transistors via selective gallium ion beam irradiation

通过镓离子束辐照调控单层MoS2晶体管的阈值电压

Baoshan Tang, Yunshan Zhao, Changjie Zhou, Mingkun Zhang, Huili Zhu, Yida Li, Jin Feng Leong, Hao Shuai, Hao Gong, Weifeng Yang(杨伟锋)

Sci China Mater, 2022, 65(3): 741–747


18

ARTICLE

Efficient broadband near-infrared phosphor Sr2ScSbO6:Cr3+ for solar-like Lighting

高效宽带近红外发光材料Sr2ScSbO6:Cr3+及其在类太阳光源中的应用

Meng Zhao, Shengqiang Liu, Hao Cai, Fangyi Zhao, Zhen Song(宋振), Quanlin Liu(刘泉林)

Sci China Mater, 2022, 65(3): 748–756


19

ARTICLE

Efficient quantum dot light-emitting diodes with ultra-homogeneous and highly ordered quantum dot monolayer

具有超均匀和高度有序量子点单层的高效量子点发光二极管

Denglin Zhao, Yueting Zheng, Tingtao Meng, Yangbin Zhu, Jipeng Jing, Xiang Chen, Hongjin Gao, Chaomin Mao, Wenchen Zheng, Hailong Hu, Tailiang Guo, Fushan Li(李福山)

Sci China Mater, 2022, 65(3): 757–763


20

ARTICLE

Te4+-doped Cs2InCl5•H2O single crystals for remote optical thermometry 

Te4+掺杂Cs2InCl5•H2O单晶的光学测温应用

Jun-Hua Wei, Jian-Bin Luo, Jin-Feng Liao, Wei-Tao Ou, Dai-Bin Kuang(匡代彬)

Sci China Mater, 2022, 65(3): 764–772


21

ARTICLE

Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency

具有[O8Pb14]簇和宽红外透过范围的Pb14O8I12和Pb7O4I6卤氧化物同质多晶

Jiahao Jiao, Abudukadi Tudi, Min Zhang(张敏), Wenbing Cai, Junjie Li, Zhihua Yang, Shilie Pan(潘世烈)

Sci China Mater, 2022, 65(3): 773–779


22

ARTICLE

Coexistence of large positive and negative magnetoresistance in Cr2Si2Te6 ferromagnetic semiconductor

Cr2Si2Te6铁磁半导体中大的正、负磁阻共存现象

Zhou Li, Wei Bai, Yuliang Li, Yuanlong Li, Sheng Wang, Weihui Zhang,

Jiyin Zhao, Zhe Sun, Chong Xiao(肖翀), Yi Xie

Sci China Mater, 2022, 65(3): 780–787



23

ARTICLE

Electron transfer photochromism of Ln-based (Ln = Dy, Tb) coordinated polymers for reversibly switching off/on single-molecule magnetic behavior

Ln基(Ln = Dy, Tb)配合物的电子转移光致变色及其可逆开关单分子磁体行为

Qian Zhang, Song-De Han, Qi Li, Ji-Xiang Hu(胡继祥), Guo-Ming Wang(王国明)

Sci China Mater, 2022, 65(3): 788–794


24

ARTICLE

Wide-range-adjusted threshold voltages for E-mode AlGaN/GaN HEMT with a p-SnO cap gate

基于p-SnO帽层栅的高阈值增强型AlGaN/GaN HEMTs

Dazheng Chen(陈大正), Peng Yuan, Shenglei Zhao, Shuang Liu, Qian Xin,Xiufeng Song, Shiqi Yan, Yachao Zhang, He Xi, Weidong Zhu, Weihang Zhang, Jiaqi Zhang, Hong Zhou, Chunfu Zhang, Jincheng Zhang(张进成), Yue Hao

Sci China Mater, 2022, 65(3): 795–802


25

ARTICLE

Sandwich layered double hydroxides with graphene oxide for enhanced water desalination

氧化石墨烯保护层稳定水滑石并用于海水淡化

Lili Wang, Zijian Yuan, Yuhui Zhang, Wei Guo(郭维), Xiaoming Sun(孙晓明), Xue Duan

Sci China Mater, 2022, 65(3): 803–810


26

ARTICLE

Exceptional high-strain-rate tensile mechanical properties in a CrCoNi medium-entropy alloy

CrCoNi中熵合金优异的高应变速率拉伸力学性能

Peng Gao, Zihao Ma, Ji Gu, Song Ni, Tao Suo, Yulong Li(李玉龙), Min Song(宋旼), Yiu-Wing Mai, Xiaozhou Liao(廖晓舟)

Sci China Mater, 2022, 65(3): 811–819


27

ARTICLE

In situ atomistic mechanisms of detwinning in nanocrystalline AuAg alloy

AuAg合金纳米晶去孪晶机制的原位原子尺度研究

Libo Fu, Chengpeng Yang, Yan Lu, Jiao Teng, Deli Kong, Yizhong Guo, Ze Zhang, Lihua Wang(王立华), Xiaodong Han(韩晓东)

Sci China Mater, 2022, 65(3): 820–826


28

ARTICLE

Dual-network hydrogel based on ionic nano-reservoir for gastric perforation sealing

基于纳米离子储层的双网络胃穿孔封堵水凝胶

Yuehui Yuan, Hao Wu, Xueyang Ren, Jianwu Wang, Ruiqing Liu, Benhui Hu(胡本慧), Ning Gu(顾宁)

Sci China Mater, 2022, 65(3): 827–835


29

ARTICLE

Highly sensitive light-up near-infrared fluorescent probe for detection and imaging of β-glucuronidase in human serum, living cells and tumor-bearing mice

用于血清、活细胞及小鼠荷瘤中β-葡萄糖醛酸苷酶检测成像的高灵敏点亮型近红外荧光探针

Xin Zhou, Deping Wang, Zhiyuan Gao, Mingyue He, Jiayi Hou, Hui Zhang (张辉), Guoqiang Zhang(张国强), Dan Ding, Guangxue Feng (冯光雪)

Sci China Mater, 2022, 65(3): 836–844


30

ARTICLE

Accelerated antibacterial red-carbon dots with photodynamic therapy against multidrug-resistant Acinetobacter baumannii

光动力疗法加速抗菌碳点对多耐药鲍曼不动杆菌的治疗

Weijian Liu, Hua Gu, Bei Ran, Wenkai Liu, Wen Sun, Dongping Wang, Jianjun Du, Jiangli Fan(樊江莉), Xiaojun Peng

Sci China Mater, 2022, 65(3): 845–854



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